Cool green-emissive Y2Si2O7:Tb3+ nanophosphor: auto-combustion synthesis and structural and photoluminescence characteristics with good thermal stability for lighting applications†

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dc.contributor.authorKumar, P
dc.contributor.authorSingh, D
dc.contributor.authorKadyan, S
dc.contributor.authorKumar, H
dc.contributor.authorKumar, R
dc.date.accessioned2024-10-07T09:55:09Z
dc.date.available2024-10-07T09:55:09Z
dc.date.issued2024-05
dc.description.abstractA cheap, versatile, sustainable and energy-efficient gel-combustion method was applied to develop a series of green-emitting down-converted Y2Si2O7:Tb3+ (YPS:Tb3+) nanophosphors. Employing XRD-based Rietveld refinement approach, the phase purity and crystallographic evaluation of the produced phosphor were conducted, revealing a triclinic crystal with P 1 space group. EDX and TEM analyses were performed on the synthesized samples to determine their elemental composition and morphological properties. Diffuse reflectance spectra yielded 5.61 eV and 5.79 eV optical energy band gaps for the host and the optimized (0.04 mole of Tb3+) sample, respectively. UV light has the ability to excite the nanocrystalline phosphor in an efficient manner, leading to significant luminosity qualities attributed to the radiative relaxation of 5 D4 / 7 FJ (J = 6, 5, 4, 3). The bi-exponential decay function was derived by the PL decay curves. With an activation energy of 0.2206 eV, the Y1.96Si2O7:0.04Tb3+ phosphor exhibits good thermal quenching capabilities. Improved photometric attributes including CIE coordinates, CCT and color purity confirmed the green glow, indicating a strong competitor for cool-green emission in lighting applicationsen_US
dc.identifier.urihttp://hdl.handle.net/123456789/1564
dc.titleCool green-emissive Y2Si2O7:Tb3+ nanophosphor: auto-combustion synthesis and structural and photoluminescence characteristics with good thermal stability for lighting applications†en_US
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