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Does fiscal federalism prevent or provoke secessionist conflicts? The Autonomy-Equalization Conundrum and the promise of concessionary federalism
(2024) Sharma, Chanchal Kumar
Does Fiscal Federalism Prevent or Provoke Secessionist Conflicts? This article shows that both insufficient fiscal equalisation and excessive redistribution can provoke contestations – especially when economic grievances of low- and high-income states coincide with national minorities. Fiscal federalism must strike a balance – empowering low-income states without expropriating high-income states – to prevent these contestations from escalating into con f licts. The challenge is twofold: First, designing a policy framework that discourages the perverse incentives associated with high levels of equalisation and autonomy. This may be recommended by Independent Fiscal Institutions (IFIs). However, this is not sufficient, because political incumbents – influenced by their incentives and self-interest – might resist these recommendations. Therefore, the second level challenge lies in making these recommendations work. One way is to establish institutionalised mechanisms of inter governmental negotiations which can reveal interdependencies and facilitate (a) continuous dialogue – enabling parties to align their incentives with economists’ recommendations and recognise their common interests where they had previously perceived con f licting ones, and (b) reciprocal concessions – encouraging parties to relax their dominant strategies. Intergovernmental councils with predefined principles for contestations and mandatory outputs (agreed-upon concessions) can yield an equilibrium where no party has a unilateral incentive to deviate, encapsulating the essence of negotiated cooperation and concessionary federalism.
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Wheat Omics: Advancements and Opportunities
(2023-01) Sehgal, D; Dhakate, P; Ambreen, H; Vikram, P
Plant omics, which includes genomics, transcriptomics, metabolomics and proteomics, has played a remarkable role in the discovery of new genes and biomolecules that can be deployed for crop improvement. In wheat, great insights have been gleaned from the utilization of diverse omics approaches for both qualitative and quantitative traits. Especially, a combination of omics approaches has led to significant advances in gene discovery and pathway investigations and in deciphering the essential components of stress responses and yields. Recently, a Wheat Omics database has been developed for wheat which could be used by scientists for further accelerating functional genomics studies. In this review, we have discussed various omics technologies and platforms that have been used in wheat to enhance the understanding of the stress biology of the crop and the molecular mechanisms underlying stress tolerance.
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Ulam Stability Results of Functional Equations in Modular Spaces and 2-Banach Spaces
(2023-01) Tamilvanan, K; Alkhaldi, A; Jakhar, J; Chugh, R; Jakhar, J
In this work, we investigate the refined stability of the additive, quartic, and quintic func tional equations in modular spaces with and without the ∆2-condition using the direct method (Hyers method). We also examine Ulam stability in 2-Banach space using the direct method. Additionally, using a suitable counterexample, we eventually demonstrate that the stability of these equations fails in a certain case.
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Transform diabetes care with precision medicine
(2023-10) Kannan, S; Chellappan, D; Kow, C; Pandey, M
Abstract Background and Aims: Diabetes is a global concern. This article took a closer look at diabetes and precision medicine. Methods: A literature search of studies related to the use of precision medicine in diabetes care was conducted in various databases (PubMed, Google Scholar, and Scopus). Results: Precision medicine encompasses the integration of a wide array of personal data, including clinical, lifestyle, genetic, and various biomarker information. Its goal is to facilitate tailored treatment approaches using contemporary diagnostic and therapeutic techniques that specifically target patients based on their genetic makeup, molecular markers, phenotypic traits, or psychosocial characteristics. This article not only highlights significant advancements but also addresses key challenges, particularly focusing on the technologies that contribute to the realization of personalized and precise diabetes care. Conclusion: For the successful implementation of precision diabetes medicine, collaboration and coordination among multiple stakeholders are crucial.
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The neglected continuously emerging Marburg virus disease in Africa: A global public health threat
(2023-10) Srivastava, D; Dash, R; Kutikuppala, L; Shanker, P; Sahoo, R
Abstract Background and Aim: Severe viral hemorrhagic fever (VHF) is caused by Marburg virus which is a member of the Filoviridae (filovirus) family. Many Marburg virus disease (MVD) outbreaks are reported in five decades. A major notable outbreak with substantial reported cases of infections and deaths was in 2022 in Uganda. The World Health Organisation (WHO) reported MVD outbreak in Ghana in July 2022 following the detection of two probable VHF patients there. Further, the virus was reported from two other African countries, the Equatorial Guinea (February 2023) and Tanzania (March 2023). There have been 35 deaths out of 40 reported cases in Equatorial Guinea, and six of the nine confirmed cases in Tanzania so far. Methods: Data particularly on the several MVD outbreaks as reported from the African countries were searched on various databases including the Pubmed, Scopus, and Web‐of‐science. Also, the primary data and reports from health agencies like the WHO and the Centers for Disease Control and Prevention CDC) were evaluated and the efficacy reviewed. Results: Chiroptera in general and bat species like Rousettus aegyptiacus and Hipposideros caffer in particular are natural reservoirs of the Marburg virus. MVD‐ infected nonhuman primate African fruit‐bat and the MVD‐infected humans pose significant risk in human infections. Cross‐border viral transmission and its potential further international ramification concerns raise the risk of its rapid spread and a potential outbreak. Occurrence of MVD is becoming more frequent in Africa with higher case fatality rates. Effective prophylactic and therapeutic interventions to counter this deadly virus are suggested. Conclusion: In the face of the lack of effective therapeutics and preventives against MVD, supportive care is the only available option which contributes to the growing concern and disease severity. In view of the preventive approaches involving effective surveillance and monitoring system following the “One Health” model is extremely beneficial to ensure a healthy world for all, this article aims at emphasizing several MVD outbreaks, epidemiology, zoonosis of the virus, current treatment strategies, risk assessments, and the mitigation strategies against MVD.
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The interlink between chrono-nutrition and stunting: current insights and future perspectives
(2023-12) Taslim, N; Samtiya, M
Stunting is the one factor that is responsible for the irretrievable damage to children’s mental and physical health. Stunting imitates chronic undernutrition throughout the most extreme critical stages of growth and development of a child in their early life, and due to that stunted child does not completely develop and are too short for their age. Stunting is mainly linked with brain underdevelopment, along with lifelong damaging consequences, comprising weakened mental and learning capacity, deprived performance in school during childhood, and enhanced risks of nutrition linked to chronic long-lasting ailments, such as diabetes, hypertension, diabesity, and obesity in the future. In this review, the authors mainly summarize the latest studies related to chronic nutrition and how it is related to stunting. Optimal nutrition, particularly during pregnancy and the first 24  months of a child’s life, is crucial in preventing stunting. Circadian rhythms play a significant role in maternal and fetal health, affecting outcomes such as premature birth and stunting. Maintaining a balanced diet, avoiding late night carbohydrate-heavy meals during pregnancy, and promoting breastfeeding align with the body’s biological clock, which can benefit newborns in various ways. Providing dedicated spaces for breastfeeding in public places is important to support infant health.
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Stochastic modeling and parameter estimation of turbogenerator unit of a thermal power plant under classical and Bayesian inferential framework
(2023-10) Kumar, A; Chaudhary, R; Kumar, K; Saini, M; Saini, D
The work reported in present study deals with the development of a novel stochastic model and estimation of parameters to assess reliability characteristics for a turbogenerator unit of thermal power plant under classical and Bayesian frameworks. Turbogenerator unit consists of five components namely turbine lubrication, turbine governing, generator oil system, gen erator gas system and generator excitation system. The concepts of cold standby redun dancy and Weibull distributed random variables are used in development of stochastic model. The shape parameter for all the random variables is same while scale parameter is different. Regenerative point technique and semi-Markov approach are used for evaluation of reliability characteristics. Sufficient repair facility always remains available in plant as well as repair done by the repairman is considered perfect. As the life testing experiments are time consuming, so to highlight the importance of proposed model Monte Carlo simulation study is carried out. A comparative analysis is done between true, classical and Bayesian results of MTSF, availability and profit function.
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Sr(II) and Ba(II) Alkaline Earth Metal–Organic Frameworks (AE-MOFs) for Selective Gas Adsorption, Energy Storage, and Environmental Application
(2023-01) Sharma, A; Meynen, V; Király, N; Capková, D
Two new alkaline earth metal–organic frameworks (AE-MOFs) containing Sr(II) (UPJS-15) or Ba(II) (UPJS-16) cations and extended tetrahedral linker (MTA) were synthesized and characterized in detail (UPJS stands for University of Pavol Jozef Safarik). Single-crystal X-ray analysis (SC-XRD) revealed that the materials are isostructural and, in their frameworks, one-dimensional channels are present with the size of ~11 × 10 Å2 . The activation process of the compounds was studied by the combination of in situ heating infrared spectroscopy (IR), thermal analysis (TA) and in situ high-energy powder X-ray diffraction (HE-PXRD), which confirmed the stability of compounds after desolvation. The prepared compounds were investigated as adsorbents of different gases (Ar, N2 , CO2 , and H2 ). Nitrogen and argon adsorption measurements showed that UPJS-15 has SBET area of 1321 m2 g −1 (Ar) / 1250 m2 g −1 (N2 ), and UPJS-16 does not adsorb mentioned gases. From the environmental application, the materials were studied as CO2 adsorbents, and both compounds adsorb CO2 with a maximum capacity of 22.4 wt.% @ 0 ◦C; 14.7 wt.% @ 20 ◦C and 101 kPa for UPJS-15 and 11.5 wt.% @ 0◦C; 8.4 wt.% @ 20 ◦C and 101 kPa for UPJS-16. According to IAST calculations, UPJS-16 shows high selectivity (50 for CO2/N2 10:90 mixture and 455 for CO2/N2 50:50 mixture) and can be applied as CO2 adsorbent from the atmosphere even at low pressures. The increased affinity of materials for CO2 was also studied by DFT modelling, which revealed that the primary adsorption sites are coordinatively unsaturated sites on metal ions, azo bonds, and phenyl rings within the MTA linker. Regarding energy storage, the materials were studied as hydrogen adsorbents, but the materials showed low H2 adsorption properties: 0.19 wt.% for UPJS-15 and 0.04 wt.% for UPJS-16 @ −196 ◦C and 101 kPa. The enhanced CO2/H2 selectivity could be used to scavenge carbon dioxide from hydrogen in WGS and DSR reactions. The second method of applying samples in the area of energy storage was the use of UPJS-15 as an additive in a lithium-sulfur battery. Cyclic performance at a cycling rate of 0.2 C showed an initial discharge capacity of 337 mAh g−1 , which decreased smoothly to 235 mAh g−1 after 100 charge/discharge cycles.
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Solidification and Stabilization of Spent Pine cone Biochar using Chemically Bonded Phosphate Cement
(2023) Tyagi, S; Annachhatre, A
Spent biochar is produced after adsorption of heavy metal which is hazardous by nature. A suitable disposal technique is required to prevent the leaching of heavy metals from spent biochar into the environment. This study highlights the solidification and stabilization (S/S) of copper loaded spent pine-cone biochar by chemically bonded phosphate cement (CBPC). The response surface methodology (RSM) was used to conduct S/S experiments in order to evaluate the compressive strength of CBPC products. The CBPC samples were prepared by varying biochar content (5-50 wt. %); W:S (0.15-0.3) and curing time(3-28d). Results illustrated that CBPC products containing biochar had higher compressive strength upto 12.8 MPa in comparison to CBPC without biochar i.e., upto 10.8 MPa. XRD and SEM analysis confirmed the presence of K-struvite (MgKPO4.6H2O), copper containing phases (Ca Cu-Si), copper phosphate precipitates (Cu3(PO4)2) and filling of pore spaces by spent biochar. Highest compressive strength of 12.8 MPa was obtained at an optimized biochar content of 25%, W:S of 0.18 and curing time of 28 d. The evaluation of leaching potential by TCLP illustrated that stabilization of Cu (II) upto 99.9% was achieved in CBPC product. The risk assessment study revealed that there is no significant danger due to leaching of heavy metals from final CBPC product indicating that it can be readily disposed in the hazardous landfill sites.